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Headspace solid phase microextraction for screening for the presence of resins in Egyptian archaeological samples

✍ Scribed by Sandrine Hamm; Jean Bleton; Alain Tchapla

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
846 KB
Volume
27
Category
Article
ISSN
1615-9306

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✦ Synopsis

Abstract

The aim of this study was to use headspace solid phase microextraction (SPME) to reveal the presence of resin in archaeological samples, such as mummification balms, from ancient Egypt. Experiments were first performed with fresh resins of known origin. The SPME fibre readily extracted mono‐ and sesquiterpenes and, to a lesser extent, diterpenes. Using mass spectra and retention indices of constitutive compounds, qualitative analysis of the volatile fraction allowed us to differentiate resins or gum‐resins such as myrrh, olibanum, galbanum, labdanum, mastic, and conifer resins. SPME was then successfully applied to archaeological samples from ancient Egypt in which the presence of resins was detected. Volatile components were desorbed and trapped according to the same SPME procedure as was applied to fresh resins, after a sample preparation consisting of a fine grinding.

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