The anisotropic ESR spectra of the CFsX-radical anions (X = Cl, Br, I) have been observed following 7 irradiation at 77 K of solid solutions containing up to 5 mole % of the CF3X parent compound in tetramethylsilane (TMS), neopentane, and 2-methyltetrahydrofuran. The resolution of the line component
Harmonic force fields for CF3Cl, CF3Br, and CF3I
โ Scribed by John H. Carpenter; John D. Muse; John G. Smith; Simon W. Walters; David H. Whiffen
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 364 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The processes of vibrational relaxation and unimolecular dissociation of the perfluoromethyl halides CF 3 Cl, CF 3 Br, and CF 3 I have been studied in the shock tube with the laserschlieren technique. Vibrational relaxation was resolved in pure CF 3 Cl and CF 3 Br (400-484 K and 400-500 K, respectiv
Translational energy release in dissociative electron attachment to CHSI, CD31, CF,I and CF,BR has been investigated at subthermal electron energies using K(nd) Rydberg atoms and a novel time-or-flight technique incorporating position-sensitive detection of the ions. The data show that, for each tar