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Halomethylmetal compounds. XVII. The mechanism of dichlorocarbene insertion into the Si-H bond by the mercurial route

✍ Scribed by Seyferth, Dietmar.; Damrauer, Robert.; Mui, Jeffrey Yick-Pui.; Jula, Theodore F.


Book ID
126193913
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
601 KB
Volume
90
Category
Article
ISSN
0002-7863

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Mechanism of metal-carbenoid insertion i
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Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i