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Halogenohydrido and halogenocarbonyl-hydrido complexes of rhenium

✍ Scribed by M. Freni; D. Giusto; P. Romiti; E. Zucca

Book ID
118907292
Publisher
Elsevier Science
Year
1969
Weight
419 KB
Volume
31
Category
Article
ISSN
0022-1902

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The five-coordinate compound [RuHCl(CO)(PiPr 2 Ph) 2 ] (1), [RuHCl 2 (CO)(PiPr 2 Ph) 2 ] -contains the chloro ligands in cis and the phosphanes in trans disposition. The Ru=CH 2 bond which was prepared from RuCl 3 β€’ 3 H 2 O and PiPr 2 Ph in methanol in the presence of NEt 3 , reacts with CO and wit