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HALOGENATION. XI. CHLORINATION WITH AQUA REGIA. THE CHLORINATION OF HYDROCARBONS.

✍ Scribed by Datta, Rasik Lal; Fernandes, Francis Vito

Book ID: 126397424
Publisher: American Chemical Society
Year: 1916
Tongue: English
Weight: 324 KB
Volume: 38
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja02266a016

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The kinetics of liquid phase chlorination of methane in a difluorodichloromethane medium has been studied in a temperature interval of 293-150 K. The value of activation energy found for the hydrogen abstraction stage by a chlorine atom (El) equals 14.2 \* 2.5 kJ/mol, with the processes of chlorine