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Halogenated carbonyl ylides in the reactions of mercurial dihalocarbene precursors with substituted benzaldehydes

โœ Scribed by Martin, Charles W.; Lund, Paul R.; Rapp, Erich; Landgrebe, John A.


Book ID
127331697
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
883 KB
Volume
43
Category
Article
ISSN
0022-3263

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Carbonyl ylide formation in the reaction
โœ Nicholas J. Turro; Yuan Cha ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Photolysis of diazomethane in acetone yields a carbonyl ylide as an intermediate. The reaction of carbene with nitriles' and ketones2 to form the corresponding ylides has received considerable attention. In nitrile solvent, methylene (CH2) has been found to react with the nitrile to form nitrile yl