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Carbonyl ylide formation in the reaction of methylene with acetone

✍ Scribed by Nicholas J. Turro; Yuan Cha

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 130 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95404-2

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✦ Synopsis

Photolysis of diazomethane in acetone yields a carbonyl ylide as an intermediate.

The reaction of carbene with nitriles' and ketones2 to form the corresponding ylides has received considerable attention. In nitrile solvent, methylene (CH2) has been found to react with the nitrile to form nitrile ylide, which is detectable by spectroscopy and product analysis.3

The formation of carbonyl ylide from methylene reaction with ketone has been proposed as an intermediate in the reaction with acetone 4 and formaldehyde, 5 respectively. We now report the results

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