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Halogenated 7-deazapurine nucleosides: stereoselective synthesis and conformation of 2?-deoxy-2?-fluoro-?-d-arabinonucleosides

✍ Scribed by Peng, Xiaohua; Seela, Frank

Book ID: 121007205
Publisher: Royal Society of Chemistry
Year: 2004
Tongue: English
Weight: 250 KB
Volume: 2
Category: Article
ISSN: 1477-0520
DOI: 10.1039/B409648G

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## Abstract Convergent syntheses of the 9‐(3‐X‐2,3‐dideoxy‐2‐fluoro‐__β__‐D‐ribofuranosyl)adenines **5** (X=N~3~) and **7** (X=NH~2~), as well as of their respective __α__‐anomers **6** and **8**, are described, using methyl 2‐azido‐5‐__O__‐benzoyl‐2,3‐dideoxy‐2‐fluoro‐__β__‐D‐ribofuranoside (**4**