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Halogen substitution reactions in halogen derivatives of cyclopentadienyltricarbonylmanganese and -rhenium at the metalcarbonyl anions

โœ Scribed by G. Z. Suleimanov; V. I. Sokolov; O. A. Reutov


Book ID
112440982
Publisher
Springer
Year
1978
Tongue
English
Weight
53 KB
Volume
27
Category
Article
ISSN
1573-9171

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Rate constants of reactions of chlorine
โœ G. B. Sergeev; V. V. Smirnov; E. V. Porodenko; A. V. Pukhovsky ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 511 KB

The kinetics of liquid phase chlorination of methane in a difluorodichloromethane medium has been studied in a temperature interval of 293-150 K. The value of activation energy found for the hydrogen abstraction stage by a chlorine atom (El) equals 14.2 \* 2.5 kJ/mol, with the processes of chlorine