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Halogen-substituted pyridines. 3. Cyclization of adducts of α,α-dichloropropionitrile with acrylic derivatives to chloropyridines

✍ Scribed by M. -G. A. Shvekhgeimer; K. I. Kobrakov; S. S. Sychev; V. K. Promonenkov


Book ID
104783270
Publisher
Springer US
Year
1989
Tongue
English
Weight
449 KB
Volume
25
Category
Article
ISSN
0009-3122

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✦ Synopsis


Reactions of ~,~-dichloropropionitrile with acrylic derivatives in the presence of CuaCI 2 gave a series of substituted 2,4-dichloro-and 2-chloro-5-oxoalkanonitriles. Their cyclization to chloropyridines has been studied.


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✍ I. A. EL-SAKKA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

Reaction of Some α-Oxophenylhydrazones with 2-Amino-1,1,3tricyanopropene and Diethyl 1-Cyano-2-aminopropene-1,3dicarboxylate: Synthesis of Polyfunctionally Substituted Pyridine, Pyridazine and Cinnoline Derivatives. -Hydrazones (I) and (VII) react with enaminonitrile (II) to yield pyridopyridine (I