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Halide catalysis of the oxidative addition of alkyl halides to rhodium(I) complexes

โœ Scribed by Forster, Denis

Book ID
124054553
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
263 KB
Volume
97
Category
Article
ISSN
0002-7863

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IK(I)-and Rh(I)-complexes react with CF3-halides to give oxidative addition products. In the reaction of IrX(CO)(PEt3)2 with CF31, X = Cl, Br, I, and with CF3Br, X = Cl, Br, only the tram addition products are formed.