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Stereochemistry of oxidative addition of alkyl halides to palladium(0) complexes

โœ Scribed by Lau, K. S. Y.; Fries, R. W.; Stille, J. K.

Book ID
127314656
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
459 KB
Volume
96
Category
Article
ISSN
0002-7863

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โœ Jutand, Anny (author);Pytkowicz, Julien (author);Roland, Sylvain (author);Mangen ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Walter de Gruyter GmbH ๐ŸŒ English โš– 400 KB

Bis-__N__-heterocyclic carbenes Pd^0^ complexes, Pd^0^(NHC)~2~, are efficient catalysts in Heck reactions performed with aryl bromides or chlorides. The Pd^0^(NHC)~2~ that are not stable are generated in situ from Pd^II^ precursors PdY~2~(NHC)~2~ (Y = halides) after a chemical reduction. The latter