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Halichondrin B: Synthesis of the C1−C22 Subunit

✍ Scribed by Lambert, William T.; Hanson, Gregory H.; Benayoud, Farid; Burke, Steven D.

Book ID
120360951
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
475 KB
Volume
70
Category
Article
ISSN
0022-3263

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An expeditious synthesis of the C(1)-C(14) subunit of halichondrin B
✍ Steven D. Burke; Kyung Woon Jung; Jeannie R. Phillips; Roman E. Perri 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 286 KB

The synthesis of he C(l)-C(14) segment 1 of hakhondtin B was achieved efficient&. Featured are the pinacof rearrangement of a-hydroxymesylate 0. the intramolecular Michael addition of 11, and the one-pot muftfstep mnversion of 73 to 1.