Half-sandwich complexes with intramolecular amino group coordination: synthesis and structure of cationic molybdenum dienyl complexes
โ Scribed by Tein-Fu Wang; Yuh-Sheng Wen
- Book ID
- 107812166
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 500 KB
- Volume
- 439
- Category
- Article
- ISSN
- 0022-328X
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## Abstract We present the synthesis and characterization of disilaโ and distanna __ansa__ halfโsandwich complexes of Groupโ 6 transition metals. These compounds exhibit high ring strain within the __ansa__ bridge, which is the key factor for the insertion of elemental chalcogens.
## Abstract We present the synthesis and characterization of the firsttrisilaโbridged __ansa__ halfโsandwich complexes of Group 6 transition metals in a oneโstep synthesis from dilithiatedprecursors Li[M(ฮท^5^โC~5~H~4~Li)(CO)~3~] (M = W, Mo) by use ofstoichiometric amounts of Si~3~Me~6~Cl~2~ under d