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Haldane gap observation in TMNIN by electron spin resonance

✍ Scribed by M. Sieling; W. Palme; B. Lüthi; T.M. Brill; J.P. Boucher; J.P. Renard

Book ID: 113319423
Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 166 KB
Volume: 140-144
Category: Article
ISSN: 0304-8853
DOI: 10.1016/0304-8853(94)01096-x

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## Abstract The rearrangement of the 2‐methyl‐2‐phenylpropyl (or neophyl) radical **1** to the 1‐methyl‐1‐benzylethyl radical **2** is observed by ESR. spectroscopy during photolysis of di‐__t__‐butylperoxide in __t__‐butylbenzene at 270–360 K. The energy of activation of the rearrangement is deter