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Hadamard long-range proton-carbon coupling constant measurements with band-selective proton decoupling

✍ Scribed by T. Nishida; G. Widmalm; P. Sandor

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
255 KB
Volume
33
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Long‐range ^13^C^1^H coupling constants were measured by using multiple‐site selective excitation followed by polarization transfer and acquisition under band‐selective proton decoupling conditions. The multiple‐site proton decoupling eliminates splittings due to homonuclear spin couplings, thereby in practice simplifying the measurement of coupling constants from the anti‐phase splittings. In addition, the sensitivity is improved by approximately 50%.

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