The solution-mediated syntheses, single-crystal structures, and some physical properties of the first 1,3-diammonium-propane zinc phosphates, H 3 N(CH 2 ) 3 NH 3 • Zn 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 and H 3 N(CH 2 ) 3 NH 3 • Zn(HPO 4 ) 2 , are described. Both phases contain vertex-sharing ZnO 4 and (H 2
H3N(CH2)3NH3·Zn(HPO3)2 containing four-ring chains of ZnO4 tetrahedra and HPO3 pseudo pyramids
✍ Scribed by William T.A. Harrison
- Book ID
- 117780692
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 248 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1466-6049
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The solution-mediated syntheses and single-crystal structures of (CN 3 H 6 ) 2 ' Zn 3 (HPO 3 ) 4 ' H 2 O (I) and H 3 N(CH 2 ) 3 NH 3 ' Zn 3 (HPO 3 ) 4 ' H 2 O (II) are reported. These phases contain networks of vertex-sharing ZnO 4 tetrahedra and HPO 3 pseudopyramids accompanied by organic cations a