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H1-Hg199spin-spin interaction through 5,6, and 7 bonds

✍ Scribed by V. S. Petrosyan; O. A. Reutov


Book ID
112421875
Publisher
Springer
Year
1970
Tongue
English
Weight
115 KB
Volume
19
Category
Article
ISSN
1573-9171

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Interunit, through-space 1H-19F and 13-1
✍ Toshiaki Miyake; Yoshiko Koyama πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 913 KB

## SDeoxy-Sfluoroarbekacin (1) and 5-deoxy-5,5difluoroarbekacin (2) showed inter-unit, through-space 'H-l'F spin-spin couplings at the signals for H-l', 4", 5", 6"a and 6"b with F-5cq. These couplings were detected by a new NMR method, 'H-detected 2D rH-"F chemical shift correlation spectroscopy.