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Guanidine/Azole Binary System as an Efficient Catalyst for Morita–Baylis–Hillman Reaction

✍ Scribed by Prof. Dr. Masahiro Terada; Satoko Fukuchi; Kei Amagai; Dr. Megumi Nakano; Dr. Hitoshi Ube

Book ID
112019354
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
307 KB
Volume
4
Category
Article
ISSN
1867-3880

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A convenient method for Morita-Baylis-Hillman reaction of arylaldehydes with methyl acrylate has been developed by using fluorous-tag organocatalyst 1-[4-(perfluorooctyl)phenyl]-3-phenylthiourea and DABCO at room temperature. The fluorous organocatalyst could be recovered from the reaction mixture b