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Guaianolides. 2. total synthesis of (±)-compressanolide and (±)-estafiatin

✍ Scribed by A.A. Devreese; M. Demuynck; P.J. De Clercq; M. Vandewalle


Book ID
108372684
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
700 KB
Volume
39
Category
Article
ISSN
0040-4020

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Guaianolides : The total synthesis of (±
✍ M. Demuynck; A.A. Devreese; P.J. De Clercq; M. Vandewalle 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 249 KB

An efficient synthesis of the trans fused perhydroazulenic epoxy ketone 2 is described. The potentiality of 2 is illustrated by its transformation into cf)-estafiatin 1. Despite a long history, a wide distribution in nature, and extensive studies in relation to interconversions with other sesquiter