Ground states of .sigma.-bonded molecules. XV. Barriers to rotation about carbon-carbon bonds
β Scribed by Dewar, Michael J. S.; Kohn, M. C.
- Book ID
- 111888634
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 689 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Barriers to rotation about the preferred axis, C-4-Hg-C-4, were determined for diphenyl-, bis(o-toly1)-and bis(m-toly1)-mercury from 13C T , relaxation times as a function of temperature in DMSO and in 1,1,2,2-tetrachloroethane-CCt,. Based on results for the unsymmetrical compound phenyl(o-tolyl)mer
Although there exists a large amount of data regarding the barrier to rotation about carbon-nitrogen bonds possessing greater than single-bond order, 1 relatively little information is available concerning rotation about legitimate carbon-nitrogen single bonds. Microwave spectroscopy has revealed r
## Barriers to rotation about carbon-carbon single bonds are, in general, so small') that isomers due to restricted rotation cannot be isolated at room