✦ LIBER ✦

Ground electronic states of ZrO+, HfO+, and Nb+2. ESR spectra of the matrix-isolated ions

✍ Scribed by R.J. Van Zee; S. Li; W. Weltner Jr.

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 558 KB
Volume: 217
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)e1412-a

No coin nor oath required. For personal study only.

✦ Synopsis

ZrO+, HfO+, and Nb$ molecular ions formed during laser-vaporization of their respective metals and/or oxides were trapped in rare-gas matrices at 4 K. X-band ESR spectra exhibited characteristic metal hypertine splittings and indicated that each ion has a 2C ground state. The derived magnetic parameters and spin characteristics for ZrO+ and Nb: are discussed relative to the corresponding neutral diatomics. Analysis of the HfW spectra was incomplete, only g, could be accurately determined.

📜 SIMILAR VOLUMES

Effect of Substitution on the ESR Spectr

Effect of Substitution on the ESR Spectra and Electronic Ground State of ZnTPP Cation Radicals

✍ Paresh C. Dave; D. Srinivas 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 393 KB 👁 2 views

Zinc(II) complexes of substituted tetraphenylporphyrins, Zn[T(X-P)P], where X = H, p-F, p-Cl, m-Cl, p-CH 3 O, and m-CH 3 O, have been synthesized and characterized. Peripheral substitution shows marked changes in the chemical shifts of the phenyl proton resonances and E 1/2 values of the redox coupl

The electronic spectra of gas-phase and

The electronic spectra of gas-phase and matrix-isolated Ag2 below 5.5 eV

✍ Roger Grinter 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 624 KB

The electronic structure, spectra, and m

The electronic structure, spectra, and magnetic properties of actinyl ions: Part II. Neptunyl, and the ground states of other actinyls

✍ S.P. McGlynn; J.K. Smith 📂 Article 📅 1961 🏛 Elsevier Science 🌐 English ⚖ 605 KB

The O 1s x-ray absorption spectra of tra

The O 1s x-ray absorption spectra of transition-metal oxides: The TiO2−ZrO2−HfO2 and V2O5−Nb2O5−Ta2O5 series

✍ L. Soriano; M. Abbate; J.C. Fuggle; M.A. Jiménez; J.M. Sanz; C. Mythen; H.A. Pad 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 299 KB

Isotropic and solid-state esr spectra of

Isotropic and solid-state esr spectra of the radical ion pairs of 2,4,6-Tri-tert-butyl thiobenzaldehyde

✍ Angelo Alberti; Gian Franco Pedulli; Giuseppe Placucci 📂 Article 📅 1991 🏛 Elsevier Science ⚖ 479 KB

Ground-state splitting and structure of

Ground-state splitting and structure of the 1, 2, 3 trifluorobenzene radical cation from low-temperature gas phase and matrix spectra

✍ V.E. Bondybey; J.H. English; Terry A. Miller 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 226 KB