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Ground- and Excited-State Dynamics of Aluminum and Gallium Corroles

✍ Scribed by Kowalska, Dorota; Liu, Xia; Tripathy, Umakanta; Mahammed, Atif; Gross, Zeev; Hirayama, Satoshi; Steer, Ronald P.


Book ID
120892145
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
964 KB
Volume
48
Category
Article
ISSN
0020-1669

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Singlet and triplet excited state data on two new core-modified expanded porphyrins and their protonated derivatives are reported. Absorption spectral studies indicate a gradual red shift of the absorption bands upon sulfur substitution into the core. The singlet lifetimes for expanded S~3~-sapphyri