Replacing the 3- and 3''-protons of the ligand 2,6-di(pyrazol-1-yl)pyridine L by mesityl groups changes the electronic ground state of [Cu(L) ] complexes from {d x 2-y 2} to {d z 2} . This is the best example so far for a "homoleptic" Jahn-Teller-compressed six-coordinate Cu complex.
Revisiting the Electronic Ground State of Copper Corroles
✍ Scribed by Martin Bröring; Frédérique Brégier; Esther Cónsul Tejero; Christian Hell; Max C. Holthausen
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 210 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0044-8249
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