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Grignard Reactions. XX. 1 Effect of Cuprous Chloride on the Reaction of t -Butylmagnesium Chloride and Trimethylacetyl Chloride

โœ Scribed by Cook, Newell C.; Percival, William C.


Book ID
125849648
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
245 KB
Volume
71
Category
Article
ISSN
0002-7863

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Substituent effects on the reaction of t
โœ Ryan E. Oyler; Benjamin E. Ketz; Timothy E. Glass ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 77 KB

The result of the substitution of trityl chlorides with Grignard reagents was found to be highly dependent on the solvent and the nature of the substituents on the trityl group. In THF, electron donating substituents were found to give high yields of Grignard addition while electron withdrawing subs