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Grignard Addition to Aldonitrones. Stereochemical Aspects and Application to the Synthesis of C 2 -Symmetric Diamino Alcohols and Diamino Diols

โœ Scribed by Dondoni, Alessandro; Perrone, Daniela; Rinaldi, Marilisa


Book ID
120411576
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
179 KB
Volume
63
Category
Article
ISSN
0022-3263

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โœ Qianyong Xu; Hui Wang; Xinfu Pan; Albert S.C Chan; Teng-kuei Yang ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 68 KB

The C 2 -symmetrical bis-b-amino alcohols 1-6 were prepared and especially attention is focused on bridges, which link the two b-amino alcohol units. These ligands have been applied as chiral catalysts in the asymmetric addition of diethylzinc to aldehydes. sec-Alcohols have been obtained in good yi