Green synthesis of a typical chiral stationary phase of cellulose-tris(3, 5-dimethylphenylcarbamate)
β Scribed by Liu, Run-Qiang; Bai, Lian-yang; Zhang, Yi-Jun; Zhang, Yu-Ping
- Book ID
- 121630929
- Publisher
- Chemistry Central
- Year
- 2013
- Tongue
- English
- Weight
- 270 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1752-153X
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## Abstract A novel cellulose tris(__N__β3,5βdimethylphenylcarbamate) (CDMPC) chiral stationary phase (CSP) was prepared by coating CDMPC on TiO~2~/SiO~2~, which was prepared by coating titania nanoparticles on silica through a selfβassemble technique. At first, 2βhydroxylβphenyl acetonitrile and _
Cellulose-tris(3,5-dimethylphenylcarbamate) was prepared after a reported method and was coated onto an aminopropylated mesopore spherical silica gel. The final product was used as a chiral stationary phase of high performance liquid chromatography for the enantioseparation of a series of glycerin s