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Green Catalysis: Hydroxycarbonylation of Aryl Halides in Water Catalyzed by an Amphiphilic Resin-Supported Phosphine−Palladium Complex

✍ Scribed by Uozumi, Yasuhiro; Watanabe, Toshihiro


Book ID
120675045
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
57 KB
Volume
64
Category
Article
ISSN
0022-3263

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Allylic substitution in water catalyzed
✍ Hiroshi Danjo; Daiki Tanaka; Tamio Hayashi; Yasuhiro Uozumi 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 732 KB

New amphiphilic resin-supported triarylphosphines PEP (1) were designed and prepared on polyethylene glycol-polystyrene graft copolymer (PEG-PS). Palladium complexes of 1, Pd(PEP)2 (4) and Pd(PEP) (5), catalyzed allylic alkylation of 3-acetoxy-1,3-diphenyl-1-propene (6) and cinnamyl acetate (7) with