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Grafting of maleic anhydride onto polypropylene by reactive extrusion

✍ Scribed by S. H. P. Bettini; J. A. M. Agnelli


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
571 KB
Volume
85
Category
Article
ISSN
0021-8995

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## SYNOPSIS Isotactic polypropylene was grafted with maleic anhydride using benzoyl peroxide as an initiator and toluene as a solvent. Effects of various parameters such as monomer and initiator concentration, reaction time, and reaction temperature on percentage grafting were studied. Effect of v

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Grafting reactions were performed in a Haake torque rheometer, according to a central composite experimental design, where the maleic anhydride and peroxide concentrations, rotor speed, and reaction time were varied. The 27 formulations were analyzed by Fourier transformed infrared spectroscopy and

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## Abstract **Summary:** Interfacial adhesion between fibers and matrix is a crucial factor for effective stress transfer from matrix to fiber; especially in short fiber reinforced composite systems. The use of a chemical compatibilizer is an efficient means to achieve such adhesion. Maleic anhydri

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Grafting of maleic anhydride onto polypropylene was performed in a Haake torque rheometer, according to a central composite experimental design, in which four factors were varied: the maleic anhydride and peroxide concentrations, rotor speed, and reaction time. The current article investigates the e