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Gradient selection in inverse heteronuclear correlation spectroscopy

✍ Scribed by Wieland Willker; Dieter Leibfritz; Rainer Kerssebaum; Wolfgang Bermel

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
460 KB
Volume
31
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

After a brief theoretical description, new gradient‐selected, proton‐detected heteronuclear correlation sequences are introduced. The gs‐HMBC and gs‐Relayed‐HMQC are closely related to the original gs‐HMQC proposed by Hurd and John. A new approach to obtain pure absorption line shapes in gradient selected spectroscopy is used to measure phase‐sensitive gs‐HMQC spectra, to carry out multiplicity editing in HSQC spectra and to distinguish direct and long‐range correlations in HMQC/HSQC–TOCSY spectra.

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