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Gradient- and Sensitivity-Enhanced Heteronuclear Multiple-Quantum Correlation Spectroscopy

✍ Scribed by Guang Zhu; Xiangming Kong; Konghong Sze

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
84 KB
Volume
135
Category
Article
ISSN
1090-7807

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✦ Synopsis

A gradient-and sensitivity-enhanced HMQC experiment has been developed. The sensitivity of the experiment is increased by factors of ͌ 2 and 2 over the conventional and gradient-enhanced HMQC experiments, respectively. This improvement is achieved by retaining both the x and the y magnetization components in the indirectly detected dimension. This experiment will be particularly useful in NMR studies of large biomolecules as the relaxation time of the multiple-quantum coherence is much longer than that of the singlequantum coherence in the slow motion limit.

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