Gradient programming and combined gradient-pressure programming in supercritical fluid chromatography
β Scribed by Ann Lisbeth Blilie; Tyge Greibrokk
- Book ID
- 108335980
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 382 KB
- Volume
- 349
- Category
- Article
- ISSN
- 1873-3778
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## Abstract A versatile and simple system is described that allows variation of the column flow rate in openβtubular capillary supercritical fluid chromatography using both onβcolumn and postcolumn detection. The system is based on columnβeffluent splitting in a lowβdeadβvolume T piece at the colum
The theoretical and practical implications of simultaneous temperature/pressure and synchronized density/temperature programming are considered. Examples are shown for separations of dimethylpolysiloxanes where these techniques provide superior separation over their analogous isothermal programming