Cluster molecular models of VO x /TiO 2 catalytic system based on embedding process of V-ion in the anatase support were considered. Cluster structures of (0 0 1) anatase surface, containing one-and two-layer were constructed and isomorphous substitution of two Ti-ions on two V-ions were calculated.
Gold/iron carbonyl clusters as precursors for TiO2 supported catalysts
✍ Scribed by Stefania Albonetti; Rosa Bonelli; Joseph Epoupa Mengou; Cristina Femoni; Cristina Tiozzo; Stefano Zacchini; Ferruccio Trifirò
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 757 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0920-5861
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✦ Synopsis
A series of supported gold/iron catalysts has been prepared from bimetallic carbonyl clusters and characterized to determine how the nature of the precursors and the thermal treatment conditions affected the dispersion of the active phase and the catalytic activity. The chemical-physical characterization, and the catalytic tests carried out, evidenced that the deposition of bimetallic Au/Fe carbonyl clusters on a titania support, and their following controlled decomposition, is a way to obtain stable catalysts, active in the decomposition of toluene.
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