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Gold(III) bis-thiosemicarbazonato complexes: synthesis, characterization, radiochemistry and X-ray crystal structure analysis

✍ Scribed by Brienne N. Bottenus; Para Kan; Tyler Jenkins; Beau Ballard; Tammy L. Rold; Charles Barnes; Cathy Cutler; Timothy J. Hoffman; Mark A. Green; Silvia S. Jurisson


Book ID
116799367
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
292 KB
Volume
37
Category
Article
ISSN
0969-8051

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Treatment of two equivalents of crs-5,15-bis(o-[2-nicotinoylamido]phenyl-2,8,12,18-tetraethyl-3,7,13,17-tetramethy~porphyrinato nickel(II), [Ni(DPE)-(NH-CO-py)& with [M(DMSO),](CIO,), in methanol produces trmuclear complexes, [Ni(DPE)-(NH-CO-py)&M(ClO& where M is Pd or Pt. The trinuclear Ni,Pd compl