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Synthesis, characterization and X-ray crystal structures of polyether and ethylene bridged bis(azolyl) platinum(II) complexes

✍ Scribed by Mairéad E. Kelly; Santiago Gómez-Ruiz; Dirk Steinborn; Christoph Wagner; Harry Schmidt


Publisher
Springer
Year
2008
Tongue
English
Weight
266 KB
Volume
33
Category
Article
ISSN
0340-4285

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The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H