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Gold(I)-Catalyzed [4+2] Annelation/Nucleophilic Addition Sequence: Stereoselective Synthesis of Functionalized Bicyclo[4.3.0]nonenes

✍ Scribed by Sebastian Böhringer; Fabien Gagosz


Book ID
118281230
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
312 KB
Volume
350
Category
Article
ISSN
1615-4150

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Gold-Catalyzed Synthesis of Bicyclo[3.2.
✍ Chun-Yao Yang; Chiou-Dong Wang; Shu-Fan Tian; Rai-Shung Liu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB 👁 1 views

## Abstract This work reports the novel gold‐catalyzed [3+2]/[2+2]‐annulation of allylsilane with 4‐methoxybut‐2‐yn‐1‐ols that yields highly strained bicyclo[3.2.0]heptene products efficiently and stereoselectively.