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Gold Complexes with Selenium Ligands, IV(1) Preparation, Crystal Structures and Reactions of Phosphine(selenourea)gold(I) Complexes

✍ Scribed by Jones, Peter G. ;Thöne, Carsten

Publisher
Wiley (John Wiley & Sons)
Year
1991
Tongue
English
Weight
431 KB
Volume
124
Category
Article
ISSN
0009-2940

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## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5‐disubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their