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Gold chemistry with ferrocene derivatives as Ligands

✍ Scribed by M Concepción Gimeno; Antonio Laguna

Book ID
105734666
Publisher
World Gold Council
Year
1999
Tongue
English
Weight
843 KB
Volume
32
Category
Article
ISSN
0017-1557

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The [Re(CO)6]+ Cation as a Ligand-Transf
The [Re(CO)6]+ Cation as a Ligand-Transfer Reagent with Ferrocene Derivatives
✍ Siden Top; Stéphane Masi; Gérard Jaouen 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB 👁 2 views

The [Re(CO) 6 ] + cation is a stable compound, soluble in aqueous media. We show that it can be used as a reagent in the synthesis of tricarbonyl(cyclopentadienyl)rhenium complexes. [Re(CO) 6 ] + reacts with ferrocene derivatives, particularly acetylferrocene, in DMSO, DMF or a water/DMSO (1:1)