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Gold-Catalyzed Intramolecular Redox Reaction of Sulfinyl Alkynes: Efficient Generation of α-Oxo Gold Carbenoids and Application in Insertion into R—CO Bonds.

✍ Scribed by Guotao Li; Liming Zhang

Book ID: 102011244
Publisher: John Wiley and Sons
Year: 2007
Weight: 45 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200743032

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Gold-Catalyzed Intramolecular Redox Reac

Gold-Catalyzed Intramolecular Redox Reaction of Sulfinyl Alkynes: Efficient Generation of α-Oxo Gold Carbenoids and Application in Insertion into RCO Bonds

✍ Guotao Li; Liming Zhang 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB

Scheme 1. a) Nucleophilic/electrophilic reactivity of a Au alkyne complex. b) Generation of an a-oxo gold carbenoid by the reaction of a Au alkyne complex with an oxygen-delivering oxidant.

Gold-Catalyzed Intramolecular Redox Reac

Gold-Catalyzed Intramolecular Redox Reaction of Sulfinyl Alkynes: Efficient Generation of α-Oxo Gold Carbenoids and Application in Insertion into RCO Bonds

✍ Guotao Li; Liming Zhang 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB