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Gold-Catalyzed Intramolecular Redox Reaction of Sulfinyl Alkynes: Efficient Generation of α-Oxo Gold Carbenoids and Application in Insertion into RCO Bonds

✍ Scribed by Guotao Li; Liming Zhang

Book ID: 101563498
Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 144 KB
Volume: 46
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200701449

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Scheme 1. a) Nucleophilic/electrophilic reactivity of a Au alkyne complex. b) Generation of an a-oxo gold carbenoid by the reaction of a Au alkyne complex with an oxygen-delivering oxidant.

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