𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Gold-Catalyzed Benzylic CH Activation at Room Temperature

✍ Scribed by A. Stephen K. Hashmi; Sascha Schäfer; Michael Wölfle; Cesar Diez Gil; Peter Fischer; Antonio Laguna; M. Carmen Blanco; M. Concepción Gimeno

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
118 KB
Volume
46
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Room-Temperature Palladium-Catalyzed CH
Room-Temperature Palladium-Catalyzed CH Activation: ortho-Carbonylation of Aniline Derivatives
✍ Chris E. Houlden; Marc Hutchby; Chris D. Bailey; J. Gair Ford; Simon N. G. Tyler 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB 👁 2 views

## Abstract **Pd and CO—ureally got me!** The title reaction proceeds efficiently at 18 °C under CO (1 atm) with 5 % [Pd(OTs)~2~(MeCN)~2~] as precatalyst. Depending on the solvents used, either anthranilates or cyclic imides can be obtained in high yields (see picture, BQ=benzoquinone, Ts=4‐toluene