Gold Catalysis: Phenol Synthesis in the Presence of Functional Groups.
β Scribed by A. Stephen K. Hashmi; Jan P. Weyrauch; Elzen Kurpejovic; Tanja M. Frost; Burkhard Miehlich; Wolfgang Frey; Jan W. Bats
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 19 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract Furans with diastereotopic alkynyl groups were prepared and then converted to anellated phenols in goldβcatalyzed reactions. In all cases a highly diastereoselective reaction was observed. The stereochemical outcome of the 1,3βinduction could be assigned by two independent crystal struc