✦ LIBER ✦

Gold Catalysis: Efficient 1,3-Induction with Diastereotopic Homopropargyl Alcohols in the Phenol Synthesis

✍ Scribed by A. Stephen K. Hashmi; Melissa Hamzić; Matthias Rudolph; Martin Ackermann; Frank Rominger

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 306 KB
Volume: 351
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200900402

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Furans with diastereotopic alkynyl groups were prepared and then converted to anellated phenols in gold‐catalyzed reactions. In all cases a highly diastereoselective reaction was observed. The stereochemical outcome of the 1,3‐induction could be assigned by two independent crystal structure analyses, showing a cis‐arrangement of the two alkyl substituents on the benzoanellated cyclohexene ring.

📜 SIMILAR VOLUMES

ChemInform Abstract: Gold Catalysis: Eff

ChemInform Abstract: Gold Catalysis: Efficient 1,3-Induction with Diastereotopic Homopropargyl Alcohols in the Phenol Synthesis.

✍ A. Stephen K. Hashmi; Melissa Hamzic; Matthias Rudolph; Martin Ackermann; Frank 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v