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Gold Catalysis: Oxepines from γ-Alkynylfurans

✍ Scribed by A. Stephen K. Hashmi; Elzen Kurpejović; Michael Wölfle; Wolfgang Frey; Jan W. Bats

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
163 KB
Volume
349
Category
Article
ISSN
1615-4150

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## Abstract A series of 2‐alkynylaryl epoxides were prepared by a sequence of Sonogashira coupling, Wittig olefination and epoxidation or a Darzens’ glycid ester synthesis. The conversion of these substrates with gold(I) catalysts furnished 3‐acylindenes and, in occasional cases as side‐products, t

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