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Gold Catalysis: Isolation of Vinylgold Complexes Derived from Alkynes

✍ Scribed by A. Stephen K. Hashmi; Andreas M. Schuster; Frank Rominger

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
262 KB
Volume
48
Category
Article
ISSN
0044-8249

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Reaction of the cationic binuclear gold(I) complex [(Ph 3 PAu) 2 Cl]BF 4 with w-alkynylfurans furnished phenols as the major product and anellated furans as the side-products. The analogous trimesitylphosphane complex [(Mes 3 PAu) 2 Cl]BF 4 selectively afforded only the phenols. The latter catalyst