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Glycothermal Reaction of Rare-Earth Acetate and Iron Acetylacetonate: Formation of Hexagonal ReFeO3

โœ Scribed by Masashi Inoue; Toshihiro Nishikawa; Tomohiro Nakamura; Tomoyuki Inui

Book ID
110827293
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
621 KB
Volume
80
Category
Article
ISSN
0002-7820

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ChemInform Abstract: Glycothermal Reacti
ChemInform Abstract: Glycothermal Reaction of Rare-Earth Acetate and Iron Acetylacetonate: Formation of Hexagonal LnFeO3.
โœ M. INOUE; T. NISHIKAWA; T. NAKAMURA; T. INUI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

The title compounds LnFeO3 (Ln: Er, Tm-Ln), crystallizing in the hexagonal space group P63cm of the YMnO3 structure type, are prepared by reaction of Ln(OAc)3 and Fe(acac)3 in 1,4-butanediol at 300 โ€ข C. This phase, which forms together with small amounts of Fe3O4 and/or the garnet phase, irreversibl