Glycosylidene Carbenes. Part 26. The Intramolecular F•••HO Hydrogen Bond of 1,3-Diaxial 3-Fluorocyclohexanols. -The ab-initio calculations of 3-fluorocyclohexanol and related systems concerning the F•••HO bonds are reported. The highly soluble rigid fluoro diols (D-I) and (L-I) are prepared and thei
✦ LIBER ✦
Glycosylidene Carbenes. Part 18. Insertion of glycosylidene carbenes into the SnH bond of tributyl- and triphenylstannane: A synthesis of stannoglycosides
✍ Scribed by Peter Uhlmann; Daniel Nanz; Eva Bozó; Andrea Vasella
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- German
- Weight
- 697 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
After chromatography. b, Determined from the 'H-NMR spectrum of the crude product. ') In C6D, at 300 K (the nuclei involved are 'H, I3C, and Il9Sn). b, Averaged values of the "'Sn and "'Sn coupling constants. ") With TMS as standard. d, With SnMe, as standard.
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