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Glycosylation under Thermodynamic Control: Synthesis of the Di- and the Hexasaccharide Fragments of the O-SP of Vibrio cholerae O:1 Serotype Ogawa from Fully Functionalized Building Blocks.

โœ Scribed by Roberto Adamo; Pavol Kovac


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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Methyl 4-(3-deoxy-L-glycero-tetronamido)-4,6-dideoxy-2-O-methyl-alpha-D- mannopyranoside was acetylated, and the fully protected methyl glycoside was treated with dichloromethyl methyl ether-ZnCl2 (DCMME-ZnCl2) reagent to give 3-O-acetyl-4-(2,4-di-O-acetyl-3- deoxy-L-glycero-tetronamido)-4,6-dideoxy