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Glycosylation reaction under high pressure

✍ Scribed by Makoto Sasaki; Yasuo Gama; Masahiko Yasumoto; Yutaka Ishigami

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
235 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

Glycosylation of various alcohols with 2,3,4,6-tetra-O-benzyl-a-D-glucopyranosyl bromide (1) in the presence of hindered amines under conditions of high pressure gave a-glycosides in good yield with high selectivity. Stereocontrolled glycosylation reactions are one of the most important topics in oligosaccharide synthesis and a large number of methods have been reported.' However, there still remains a strong demand to develop simple, mild, and efficient methods for the stereoselective construction of O-glycoside bond.2

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