𝔖 Bobbio Scriptorium
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Glycosylation of cardenolides. II. Strophanthidin 3β-(methyl glucosiduronate)

✍ Scribed by N. Sh. Pal'yants; N. K. Abubakirov

Book ID
112373301
Publisher
Springer
Year
1975
Tongue
English
Weight
78 KB
Volume
11
Category
Article
ISSN
0009-3130

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Regioselectivity shift from β-(1→6)- to
Regioselectivity shift from β-(1→6)- to β-(1→3)-glycosylation of non-protected methyl β-d-galactopyranosides using the stannylene activation method
✍ Eisuke Kaji; Keigo Shibayama; Kazusada In 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 153 KB

Regio-and stereoselective glycosylation of non-protected methyl b-D-galactopyranoside has been developed using the stannylene acetal mediator, allowing a one-pot assembly of glucosyl-b-( 16)-galactose and glucosyl-b-(13)-galactose. Remarkable regioselectivity shift from b-( 16)to b-(13)-glycosylatio